Wolfram Language

Acesso mais produtivo à base de conhecimento

Prepare aspirina

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A aspirina é um dos medicamentos mais comumente usado para o tratamento de dor, febre e inflamação. Ela pode ser sintetizada através da combinação de quantidades equimolares de ácido salicílico e anidrido acético. Aqui, dados químicos da Wolfram Knowledgebase são utilizados juntos com o frameworks de quantidades e grupos de entidades, cópias e exemplos, para estudar a preparação química da aspirina.

Represente um lote típico de laboratório para a preparação 100 milimolar de aspirina usando EntityGroup.

In[2]:=
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reactants = EntityGroup[{EntityInstance[Entity["Chemical", "SalicylicAcid"], Quantity[0.1, "Moles"]], EntityInstance[Entity["Chemical", "AceticAnhydride"], Quantity[0.1, "Moles"]]}]
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Calcule a massa total desse lote usando a forma "curried" de uma consulta de entidades e propriedades.

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mass = reactants["AbsoluteMass"]
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Como o anidrido acético é um líquido, seria conveniente saber exatamente quanto é necessário.

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UnitConvert[ EntityInstance[Entity["Chemical", "AceticAnhydride"], Quantity[0.1, "Moles"]]["AbsoluteVolume"], "Milliliter"]
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Supondo um estequiométrico, uma reação quantitativa por exemplo (teórica), isto produz 100 milimoles de aspirina. Porém, na prática, produz cerca de 90%.

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EntityInstance[Entity["Chemical", "Aspirin"], 0.9*Quantity[0.1, "Moles"]]["AbsoluteMass"]
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Faça a contagem dos átomos que constituem a molécula de aspirina.

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elem = Entity["Chemical", "Aspirin"]["ElementCounts"]
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Reúna os números adequados desses átomos em uma expressão de entidades agrupadas.

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atomAssemble = EntityGroup[ MapThread[EntityCopies[#1, #2] &, {Keys[elem], Values[elem]}]]
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atomicmass = atomAssemble["AtomicMass"]
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Conforme esperado, a massa atómica total deste grupo de entidades coincide com a massa molar da molécula inteira.

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molarmass = Entity["Chemical", "Aspirin"][ EntityProperty["Chemical", "MolarMass"]]
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Equal @@ QuantityMagnitude /@ {atomicmass, molarmass}
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Porém, existem outras combinações isotópicas possíveis, cada uma delas com uma massa total um pouco diferente.

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stableIsotopes = #[EntityProperty["Element", "StableIsotopes"]] & /@ Keys[elem]
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Este grupo é constituído apenas pelos isótopos padrão (o chamado "íons principais").

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EntityGroup[{EntityCopies[Entity["Isotope", "C12"], 9], EntityCopies[Entity["Isotope", "H1"], 8], EntityCopies[Entity["Isotope", "O16"], 4]}]["AtomicMass"]
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A probabilidade da ocorrência de uma molécula com tal composição é inferior a 90%. No entanto, em um espectro de massa seria o pico molecular mais proeminente.

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Times @@ MapThread[(QuantityMagnitude[#1[ EntityProperty["Isotope", "IsotopeAbundance"]], "PureUnities"])^#2 &, {stableIsotopes[[All, 1]], Values[elem]}]
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